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Mine Safety Health Administration (MSHA)

Permissible Exposure Limits

Most of the current MSHA PELs for the mining industry, cited in 30 CFR § 56.5001 and 30 CFR § 57.5001, are the ACGIH TLVs adopted in 1973.  As of February, 2017, the current MSHA PEL-TWA for respirable silica is calculated from the following formula and compared to respirable dust exposures.

10 mg/m3
(% Respirable Quartz) + 2

The MSHA PELs for cristobalite and tridymite are 1/2 the value calculated for Quartz.

Several websites that follow MSHA, such as Aggregates Manager and Lexology,  have reported that MSHA is in the process of developing a Respirable Crystalline Silica rule that will establish a new PEL for work activities subject to MSHA regulation.  The MSHA website should be consulted for updates on the Silica rule-making process.

Comparing Air Sampling Results to the MSHA PEL.

The calculated PEL (see formula above) used by MSHA is compared to the  respirable particulate results obtained from the analysis of breathing zone samples.


Example - MSHA Formula

Full shift (8-hour) air samples taken on two equipment operators yielded the following results:

Employee 1
Respirable particulate = 2.0 mg/m3
Percent silica (quartz) in sample = 4%


PEL-TWA=
10 mg/m3
4 + 2

Thus, the calculated respirable dust PEL-TWA = 1.7 mg/m3.

Employee 2
Respirable particulate = 2.0 mg/m3
Percent silica (quartz) in sample = 25%

PEL-TWA=10 mg/m3
25 + 2

Thus, the calculated respirable dust PEL-TWA = 0. 37 mg/m3.

Both employees are exposed above the calculated PELs for these samples, i.e., 2.0 mg/m3 exceeds 1.7 mg/m3 and 0.37 mg/m3.

Mixtures of Silica Types

Whenever a mixture of quartz, cristobalite and/or tridymite occurs, a special mixture calculation is performed to calculate the correct PEL. Calculating the PELs separately and comparing them to the exposure to the individual components would underestimate the hazard. 

Sample calculation for a mixture of crystalline silica:

Two consecutive samples from the same employee taken from a combined exposure to crystalline silica dusts have the following results:

SampleSampling Period (min)Total Volume
(Liters)
Respirable weight (mg)Respirable Concentration
(mg/m3)
Laboratory results (%)
A2384050.8552.15.2 Quartz
2.3 Cristobalite
ND Tridymite
B1923260.6191.94.8 Quartz
1.7 Cristobalite
ND tridymite
4307311.474
ND = None Detected

Calculation of the TWA from sampling and analytical data:

Step No. 1: Calculate the percentage of quartz, cristobalite and tridymite in the respirable particulate collected,

a. Quartz:

Percentage =(weight of quartz in Sample A) + (weight of quartz in sample B) x (100)
Total weight of respirable particulate collected
=0.052(0.855 mg) + 0.048(0.619 mg) x (100)
(0.855 mg + 0.619 mg)
=0.044 mg + 0.03 mg x (100) = 0.074 mg x (100)
1.474 mg                   1.474 mg
=0.05(100) = 5%

b. Cristobalite:

Percentage =(weight of cristobalite in sample A) + (weight of cristobalite in sample B) x (100)
Total weight of respirable particulate collected
=0.023(0.855 mg) + 0.017(0.619 mg) x (100)
1.474 mg
=0.02 mg + 0.011 mg x (100)
1.474 mg
=0.031 mg   x (100)= 0.021(100) = 2.1% = 2%
1.474 mg

c. Tridymite: None detected = 0%

Step No. 2: Calculate the PEL for the mixture (use the formula in the OSHA Technical manual Appendix I-1. 5)

PEL mixture =10 mg/m3
[% quartz + 2(% cristobalite) + 2(% tridymite) + 2]
10 mg/m3
[5.0 + 2(2.0) + 2(0) + 2]
10   = 0.91 mg/m3
11

Step No. 3: Calculate the employee's exposure to respirable dust

Exposure =(sample weight A + Sample weight B)
Total volume of air sampled
=(0.855 mg + 0.619 mg)
731 liters (1 m3/1000 liters)
=2.0 mg/m3

Step No. 4: Adjust (where necessary) for sampling period less than 8 hours. Assume a zero exposure time for the sampling period remaining.

Adjusted Exposure =(2.0 mg/m3)(430 minutes) + 0(50 minutes)
480 minutes
=2.0 mg/m3(430 minutes) = 1.8 mg/m3
480 minutes

Step No. 5: Calculate the severity of the exposure:

Severity =Adjusted Exposure
PEL mixture
=(1.8 mg/m3) = 2.0
(0.91 mg/m3)

If the result from Step 5 is greater than 1. 0, then an overexposure to the mixture of crystalline silica exists.

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ACGIH® Threshold Limit Values (TLVs®)

An internationally recognized source of occupational health standards are the Threshold Limit Values (TLVs) developed by the American Conference of Governmental Industrial Hygienists (ACGIH).  The ACGIH TLVs are published annually for use by professionals trained in the practice of industrial hygiene.  The TLVs are guidelines and are not designed to be used as standards, nevertheless, ACGIH is aware that in certain instances, the TLVs are used as standards by national, state, or local governments.

In order to minimize the potential for adverse health effects from exposure to silica, corrective actions should be taken when air sampling results show employee silica exposures exceed the recommended ACGIH TLV-TWA.  The TLV-TWA (Time Weighted Average) is that concentration for a conventional 8-hour workday and a 40-hour work week to which it is believe nearly all workers may be repeatedly exposed, day after day, for a working lifetime without adverse effect.

The TLVs are updated annually, and in 2008, the current (2016) TLV-TWA of 0.025 mg/m3 for crystalline quartz and cristobalite was published.  The current TLV-TWA for respirable silica (quartz and cristobalite) is the same as the OSHA Action Level for General Industry and Construction.  The TLV includes the A2, Suspected Human Carcinogen, notation.  This notation is based upon the demonstrated association between lung cancer and the presence of silicosis.  The TLV is more stringent than the 0.05 mg/m3 PEL for respirable crystalline silica (all forms), thus providing a higher level of protection.

Information regarding the current ACGIH TLV-TWA for silica can be obtained by contacting the ACGIH at (http://www.acgih.org/) or your Zurich Services Corporation representative
.


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TLVs for Extended Work Shifts

Application of TLVs for workers on work schedules markedly different from the conventional 8-hour day, 40-hour week requires judging the impact of extended exposure to chemicals due to extended work shifts.  The following formula, developed by Brief & Scala, reduces the TLV proportionately for both increased exposure time and reduced recovery (non-exposure) time from extended work shifts.

 TLV Reduction Factor =          8-hours           x      Hours off
                                                Hours Worked           16 hours 

For example, if the employee’s exposure time is 10 hours, the TLV reduction factor is 0.7.  Therefore, the silica TLV of 0.025 mg/m3 for 8-hours would be reduced to 0.0175 mg/m3 for 10-hours.  The OSHA PELs for crystalline silica are not adjusted for extended shift (exposure) time.

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Action Level

In order to account for variability in exposures which occurs from day to day, an Action Level is often used when initial survey results are evaluated.  The OSHA Action Level of 0.025 mg/m3 is 50% of the OSHA PEL-TWA of 0.05 mg/m3, and equal to the ACGIH TLV-TWA.  Exposures at or above the OSHA Action Level trigger specific requirements of the OSHA Silica standards.
 
Given the ACGIH TLV for crystalline quartz and cristobalite is 0.025 mg/m
3, the advisory Action Level would be 0.0125 mg/m3 for 8-hours, and lower if employees work an extended shift (See TLVs for Extended Work Shifts).  

When initial sampling results fall below the Action Level, there is a statistical basis for concluding that day-to-day variability does not result in a significant number of days where the exposure would exceed exposure limits.  Survey results between the Action Level and the exposure limit indicate a potential for a significant number of days where exposure above the PEL/TLV may be found, unless the initial sampling results represents a "worst-case" scenario.  Additional sampling may demonstrate repeated daily exposures below the PEL/TLV or a significant number of days when the PEL is exceeded. Thus exposures above the Action Level prompt action to control exposures where limited quantitative sampling data is available.


In operations where day-to-day exposures are highly variable and job conditions change rapidly, controlling exposures below the Action Level reduces the chance that the exposure limits are exceeded on higher productions days.

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